Copolymerization of eight-membered ring-opening allylic sulfide lactone and disulfide monomers with methyl methacrylate and styrene

Marisa Phelan; Fawaz Aldabbagh; Per B. Zetterlund; Bunichiro Yamada

doi:10.1016/j.eurpolymj.2006.04.011

Copolymerization of eight-membered ring-opening allylic sulfide lactone and disulfide monomers with methyl methacrylate and styrene

Marisa Phelan
, Fawaz Aldabbagh
, Per B. Zetterlund
, Bunichiro Yamada

Research output: Contribution to journal › Article › peer-review

Abstract

Apparent reactivity ratios and detailed NMR analysis of copolymerizations of eight membered ring-opening allylic sulfide monomers; 3-methylene-1,5-oxathiocan-2-one 2 and 2,2,4-trimethyl-7-methylene-1,5-dithiocane 5 with methyl methacrylate and styrene are presented. The activated double bond of 2 and unactivated double bond and additional methyl substituents of 5 were found to have a profound affect on reactivity. The copolymerization rates were analyzed based on the lumped parameter k_p(f/k_t)^0.5, which was estimated as a function of monomer composition in the feed.

Original language	English
Pages (from-to)	2475-2485
Number of pages	11
Journal	European Polymer Journal
Volume	42
Issue number	10
Early online date	12 Jun 2006
DOIs	https://doi.org/10.1016/j.eurpolymj.2006.04.011
Publication status	Published - Oct 2006
Externally published	Yes

Keywords

Copolymerization
Free radical
Ring-opening
Sulfanyl radical

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title = "Copolymerization of eight-membered ring-opening allylic sulfide lactone and disulfide monomers with methyl methacrylate and styrene",

abstract = "Apparent reactivity ratios and detailed NMR analysis of copolymerizations of eight membered ring-opening allylic sulfide monomers; 3-methylene-1,5-oxathiocan-2-one 2 and 2,2,4-trimethyl-7-methylene-1,5-dithiocane 5 with methyl methacrylate and styrene are presented. The activated double bond of 2 and unactivated double bond and additional methyl substituents of 5 were found to have a profound affect on reactivity. The copolymerization rates were analyzed based on the lumped parameter kp(f/kt)0.5, which was estimated as a function of monomer composition in the feed.",

keywords = "Copolymerization, Free radical, Ring-opening, Sulfanyl radical",

author = "Marisa Phelan and Fawaz Aldabbagh and Zetterlund, \{Per B.\} and Bunichiro Yamada",

year = "2006",

month = oct,

doi = "10.1016/j.eurpolymj.2006.04.011",

language = "English",

volume = "42",

pages = "2475--2485",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd",

number = "10",

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TY - JOUR

T1 - Copolymerization of eight-membered ring-opening allylic sulfide lactone and disulfide monomers with methyl methacrylate and styrene

AU - Phelan, Marisa

AU - Aldabbagh, Fawaz

AU - Zetterlund, Per B.

AU - Yamada, Bunichiro

PY - 2006/10

Y1 - 2006/10

N2 - Apparent reactivity ratios and detailed NMR analysis of copolymerizations of eight membered ring-opening allylic sulfide monomers; 3-methylene-1,5-oxathiocan-2-one 2 and 2,2,4-trimethyl-7-methylene-1,5-dithiocane 5 with methyl methacrylate and styrene are presented. The activated double bond of 2 and unactivated double bond and additional methyl substituents of 5 were found to have a profound affect on reactivity. The copolymerization rates were analyzed based on the lumped parameter kp(f/kt)0.5, which was estimated as a function of monomer composition in the feed.

AB - Apparent reactivity ratios and detailed NMR analysis of copolymerizations of eight membered ring-opening allylic sulfide monomers; 3-methylene-1,5-oxathiocan-2-one 2 and 2,2,4-trimethyl-7-methylene-1,5-dithiocane 5 with methyl methacrylate and styrene are presented. The activated double bond of 2 and unactivated double bond and additional methyl substituents of 5 were found to have a profound affect on reactivity. The copolymerization rates were analyzed based on the lumped parameter kp(f/kt)0.5, which was estimated as a function of monomer composition in the feed.

KW - Copolymerization

KW - Free radical

KW - Ring-opening

KW - Sulfanyl radical

U2 - 10.1016/j.eurpolymj.2006.04.011

DO - 10.1016/j.eurpolymj.2006.04.011

M3 - Article

AN - SCOPUS:33748933045

SN - 0014-3057

VL - 42

SP - 2475

EP - 2485

JO - European Polymer Journal

JF - European Polymer Journal

IS - 10

ER -

Copolymerization of eight-membered ring-opening allylic sulfide lactone and disulfide monomers with methyl methacrylate and styrene

Abstract

Keywords

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