Abstract
The first inverse dispersed phase controlled/living polymerization in supercritical carbon dioxide (scCO2) is described. The nitroxide-mediated radical polymerization of N-isopropylacrylamide proceeded in the absence of stabilizer to high conversion giving a dry powder. The polymerization and purification does not require the use of environmentally damaging volatile organic compound.
| Original language | English |
|---|---|
| Pages (from-to) | 1719-1723 |
| Number of pages | 5 |
| Journal | Journal of Polymer Science, Part A: Polymer Chemistry |
| Volume | 49 |
| Issue number | 7 |
| Early online date | 8 Feb 2011 |
| DOIs | |
| Publication status | Published - 1 Apr 2011 |
| Externally published | Yes |
Keywords
- heterogeneous
- living polymerization
- particle
- nucleation
- poly(N-isopropylacrylamide)
- radical
- polymerization
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