Photochemical aryl radical cyclizations to give (E)-3-Ylideneoxindoles

Ingrid Allart-Simon; Patrick McArdle; Stephane Gerard; Janos Sapi; Fawaz Aldabbagh; Michael Gurry

doi:10.3390/molecules191015891

Photochemical aryl radical cyclizations to give (E)-3-Ylideneoxindoles

Ingrid Allart-Simon
, Patrick McArdle
, Stephane Gerard
, Janos Sapi
, Fawaz Aldabbagh
, Michael Gurry

Research output: Contribution to journal › Article › peer-review

Abstract

(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts

Original language	English
Pages (from-to)	15891-15899
Journal	Molecules
Volume	19
Issue number	10
DOIs	https://doi.org/10.3390/molecules191015891
Publication status	Published - 30 Sept 2014

Keywords

Chemistry

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10.3390/molecules191015891

Al-Dabbagh-F-39349-VoRFinal published version, 815 KBLicence: CC BY

http://dx.doi.org/10.3390/molecules191015891

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title = "Photochemical aryl radical cyclizations to give (E)-3-Ylideneoxindoles",

abstract = "(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts",

keywords = "Chemistry",

author = "Ingrid Allart-Simon and Patrick McArdle and Stephane Gerard and Janos Sapi and Fawaz Aldabbagh and Michael Gurry",

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AU - Allart-Simon, Ingrid

AU - McArdle, Patrick

AU - Gerard, Stephane

AU - Sapi, Janos

AU - Aldabbagh, Fawaz

AU - Gurry, Michael

PY - 2014/9/30

Y1 - 2014/9/30

N2 - (E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts

AB - (E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts

KW - Chemistry

UR - http://www.mdpi.com/1420-3049/19/10/15891

U2 - 10.3390/molecules191015891

DO - 10.3390/molecules191015891

M3 - Article

C2 - 25271428

SN - 1420-3049

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SP - 15891

EP - 15899

JO - Molecules

JF - Molecules

IS - 10

ER -

Photochemical aryl radical cyclizations to give (E)-3-Ylideneoxindoles

Abstract

Keywords

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