RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

Fumi Ishizuka; Harpal S. Dhiraj; Amr Elshaer; Per B. Zetterlund; Fawaz Aldabbagh

doi:10.1039/D2PY00530A

RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

Fumi Ishizuka
, Harpal S. Dhiraj
, Amr Elshaer
, Per B. Zetterlund
, Fawaz Aldabbagh

Research output: Contribution to journal › Article › peer-review

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Abstract

Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.

Original language	English
Pages (from-to)	3750-3755
Journal	Polymer Chemistry
Volume	13
Issue number	25
Early online date	7 Jun 2022
DOIs	https://doi.org/10.1039/D2PY00530A
Publication status	Published - 7 Jul 2022

Bibliographical note

Impact: New Smart (stimuli-responsive) nanoparticles discovered with potential biomedical applications

Keywords

Metallurgy and materials

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10.1039/D2PY00530ALicence: CC BY

Dhiraj-H-51929-VoRFinal published version, 3.41 MBLicence: CC BY

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abstract = "Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.",

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author = "Fumi Ishizuka and Dhiraj, \{Harpal S.\} and Amr Elshaer and Zetterlund, \{Per B.\} and Fawaz Aldabbagh",

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AU - Ishizuka, Fumi

AU - Dhiraj, Harpal S.

AU - Elshaer, Amr

AU - Zetterlund, Per B.

AU - Aldabbagh, Fawaz

N1 - Impact: New Smart (stimuli-responsive) nanoparticles discovered with potential biomedical applications

PY - 2022/7/7

Y1 - 2022/7/7

N2 - Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.

AB - Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.

KW - Metallurgy and materials

U2 - 10.1039/D2PY00530A

DO - 10.1039/D2PY00530A

M3 - Article

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VL - 13

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EP - 3755

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 25

ER -

RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

Abstract

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