RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

Fumi Ishizuka; Harpal S. Dhiraj; Amr Elshaer; Per B. Zetterlund; Fawaz Aldabbagh

doi:10.1039/D2PY00530A

RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

Fumi Ishizuka
, Harpal S. Dhiraj
, Amr Elshaer
, Per B. Zetterlund
, Fawaz Aldabbagh

Research output: Contribution to journal › Article › peer-review

Abstract

Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.

Original language	English
Pages (from-to)	3750-3755
Journal	Polymer Chemistry
Volume	13
Issue number	25
Early online date	7 Jun 2022
DOIs	https://doi.org/10.1039/D2PY00530A
Publication status	Published - 7 Jul 2022

Bibliographical note

Impact: New Smart (stimuli-responsive) nanoparticles discovered with potential biomedical applications

Keywords

Metallurgy and materials

Access to Document

10.1039/D2PY00530A

Dhiraj-H-51929-VoRFinal published version, 3.41 MBLicence: CC BY

https://doi.org/10.1039/D2PY00530A

Cite this

@article{cc21980fdfd64bfab6aa277b587fed6c,

title = "RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides",

abstract = "Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.",

keywords = "Metallurgy and materials",

author = "Fumi Ishizuka and Dhiraj, \{Harpal S.\} and Amr Elshaer and Zetterlund, \{Per B.\} and Fawaz Aldabbagh",

note = "Impact: New Smart (stimuli-responsive) nanoparticles discovered with potential biomedical applications",

year = "2022",

month = jul,

day = "7",

doi = "10.1039/D2PY00530A",

language = "English",

volume = "13",

pages = "3750--3755",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "25",

}

TY - JOUR

T1 - RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

AU - Ishizuka, Fumi

AU - Dhiraj, Harpal S.

AU - Elshaer, Amr

AU - Zetterlund, Per B.

AU - Aldabbagh, Fawaz

N1 - Impact: New Smart (stimuli-responsive) nanoparticles discovered with potential biomedical applications

PY - 2022/7/7

Y1 - 2022/7/7

N2 - Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.

AB - Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.

KW - Metallurgy and materials

U2 - 10.1039/D2PY00530A

DO - 10.1039/D2PY00530A

M3 - Article

SN - 1759-9954

VL - 13

SP - 3750

EP - 3755

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 25

ER -

RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

Abstract

Bibliographical note

Keywords

Access to Document

Fingerprint

Cite this